I must admit I'm a little hessitant to do this now judging by the explaination there taz lol.
I have an Asus P5KR motherboard, E8400 @ 3Ghz, 2xPC5300 1 GB (which I believe is 667 Mhz).
I have the ASUS overclocking software AISuite installed and I'm staring at the screen. I really can't afford to screw this PC up, just how risky is overclocking? I have reasonable air cooling but I run this PC 24/7. If I overclock can I run it like that all the time or should I only do it for when I need the extra speed?
Here is a screenshot I took of AISuite. What temperatures should I be expecting and what temps should I be worried about?
Overclocking is easy once you get to grips with the basics and get an understanding of what all the bios setting do, everything effect everything else, that's why you need to it in stages otherwise it becomes almost impossible to work out where you when wrong. If you have questions as to what all those option in bios do, hit me with it, I'll do my best to explain, just don't ask me to explain it all at once.
Your memory will be your biggest issue, DDR2-667 like you have runs at 333mhz double pumped, so the 333mhz FSB of you CPU puts your memory at it's maximum stock speed straight away, say your aim for 4ghz with your CPU, for memory would end up almost 50% overclocked to get there, now that a big push for most memory and outside what I would rate as practical or save, you best option would be to be dump your current memory on a friend or family member with a PC in need of a bit more get up and go, and grab yourself a couple of GB of good DDR2-800 or better yet DDR2-1066 RAM. Memory is dirt cheap these days so it doesn't have to cost you the earth. Then as long as you have a good aftermarket heatsink, you should be good to go.
Software overclocking has it's place, but it doesn't give you access to nearly as many setting to adjust, so it soon limits the level of overclocking you can achive, There are a number of bios features that needed to be disable before any form or overclocking is attempted, as they will cause stability issues with an overclocked CPU, so you end up having to change BIOS settings anyway so you may as well just do it all in BIOS where you'll get the best results.
Overclocking very safe as long as you don't push things too far, too much Voltage or heat and things can get nasty, A good heatsink & Powersupply are a must. The thing to remember is the Core 2 Duo is not an Athlon XP, the Core 2 Duo has great built in safeties for heat and will shut it self down if needed before any damage is done, just be smart about it, if you crank the FSB up to 600mhz and pumping 1.8v into your CPU and having it run a 75degs you would just be asking for trouble.
Those tempatures look normal for a stock setup, I would expect lower temps if you were using an aftermarket cooler, but it depends of the room temp and the design of your case.
Taz is a better overclocker than I am, but unless he disagrees I prefer to overclock from the bios, a rule of thumb for me is 25% overclock then I usually just call it good.
dm
25% is a good overclock for most CPUs, but the Core 2 Duo is a whole other league with the average overclock falling in the 33%-75% range, they have so much head room it's basically a crime not to overclock them, you can get 25% overclocks with the stock heatsink I many cheaper models.
DM, I know you have some AMD x2 rigs - have you tried ocing your rigs, and do they do well with mame? I have a 4800+ for my mame rig.
The Athon64 x2 overclock well, the last one I had in my primary system was overclocked by about 40%, and they do well in MAME to a point, but they can't jump the preformance gulf between what is needed to run most ROM and what is required to run all ROM (well almost all). They just don't have the preformance to clock ratio that the Core 2 Duo does, and the extreme overclockablity (is that even a word) of Core 2 Duo only widens the preformace gap between the two CPUs.
If I had the spare cash laying around I'd probably grab a GA-G33M-DS2R boarch and transfer over my CPU, Heatsink and ram to it, and benchmark it to see if using the onboard graphics had any negative on MAME preformance, because if it didn't then it would be a good choice for people trying to slim down the cost of preformance MAME system. The board is well documented as a great overclocker, with people run anywhere up to 500fsb and some beyond. When the next shipment of stock comes in a work, I may have to see if I get the boss to lead me one for a week to test, it's not likely to happen but it's possible.