For your power connections (and double check this with a meter) you should have red for +5V, Yellow for -5V, Orange for +12V, and of course black for ground.
From your picture, it looks like you are missing +12V?? That's odd to me. some games you can do without the -5V, but the 12V would seem like the more likely to be there.
As for your video, it depends on what the PCB is supplying and what the monitor is looking for. I think I remember Bob Roberts saying he liked to have the RGB in a 3 pin connector, and the Syncs in a separate connector, so he could skip a pin depending on if the setup required Vert Sync, Horiz Sync, or Composite. You may need to move a pin within your connector, or make a jumper
-Stobe