Amplification can provide a clearer sound depending on the speaker, but the biggest thing amplification will do for you is make it louder. The only thing you'll get from a second speaker would be louder sound. However, without an increase in amplification to support the second speaker, you risk losing volume as well as sound clarity.
In any event, replacing the speaker you have with a better one or amplifying it more (or both) is a better option than adding a second if you only have mono sound.
The volume increase gained from a second speaker works on a logarithmic scale, but the volume increase gained from increasing the amplification is more directly proportional. In other words, you get more bang for your buck by making your one speaker better than by adding a second one.