You might want to be carefull about how many things you connect to your PC power supply. LED lights and some small speakers are fine. But you can't just hook up any 12VDC electronics. You'll want to check how much current you'll be using vs. how much the power supply is putting out.
Check the power brick for your speakers and see what kind of current it will put out. Typically whatever the rating is on the power brick, subtract about 5% and thats what your equipment will be using. Or the rating could be found directly on the lead speaker/subwoofer, or wherever the power is connected to.
You might find that you will need more current than what is supplied, you can get a bigger PC power supply, or.
You can also use 12VDC relays to switch your higher loads. Simple small single circuit relays can usually be found fairly easy at autoparts stores.