Thank you.
I appreciate the info.
I've started using the pen tool in Photoshop, and liking it.
However I'm sure my work is not the cleanest !

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That is my prime concern when your dealing with an image @ 72" tall.
When using the pen tool I also use the pencil vs the brush. From what I gather (and please correct me if wrong)
with the Anti- aliasing the pencil tool makes for a cleaner look when filled with color. IE - the white edge you had mentioned prior.....
Again, I may be incorrect, but I had seen this online. I also read that when zoomed in the pencil does not look as clean as the brush, but in print it actually looks much like the paint brush.
I've been doing my outline, then creating another layer called "color." Selecting with magic wand, then moving down to the color layer to fill.
Any additional tips and tricks are welcome.
Thank you all