CRT_Emudriver is great, but it doesn't take effect until Windows loads, so you'll probably still be at the default resolution for BIOS, which is probably 31kHz. It might not damage your monitor to display some garbage on screen while out of range, but if you really want to play it safe then wait until Windows is loaded to turn it on.
Eventually you want to set something up to automatically turn the monitor on once your front-end is loaded in Windows, like a computer controlled relay. For now just listen for a login sound and/or keep a PC monitor on hand for setup.
Also, you should ask about CRT_Emudriver or GroovyMAME in the GroovyMAME section.