I'm with SL on this one. I looked into RFID for a similar project and discovered that it's original intended use (preventing shop lifting) is about all it's good for. You can tell when a tag is within range of a scanner and the tag can hold some info, but other than that you can't really tell where the tag is, where it's pointing, ect. The beauty and downfall of rfid is that the tags are powerless and thus their signal is very sporadic and weak.
Not saying it can't be done, but your webcam approach is probably a better one. Remember, webcams can see IR so that might be of some help.