Part of the reason is due to the fact that the phosphor dot pitch typically is coarser at the edges than in the center of the tube face. This is done partially to hide the poor edge behavior (owing not only to what LilShawn said but also due to how hard it is to tweak up convergence, etc. along the edges) and is much more pronounced on a typical TV tube (used in arcade monitors) than a computer monitor tube (used, appropriately, in computer monitors).
Getting a CRT monitor to look "perfect" is darned hard. Even the multi-kilodollar workstation monitors from the late 90s weren't "perfect", but they were pretty good. The amount of factory tuning and additional circuitry required to make that happen was pretty extreme, though, which is why they cost so much.