l never like to power anything from a computer power supply especially and amp because it will amplify any noise problems, it was explained to me some time ago that computer power supplies are not always suitable because they are swithing or switch mode supplies whatever that means. Anyway the simplist and safest way of doing it l think is to buy a 12 v transformer throw a small bridge retifier on it and there u have a 12dc output, just make sure you get one big enough to handle the current requirements of your amp. If you need filtering then u will require a 9v tapped transformer, and with the filtering cap it will be retified to 12 dc output.
Run the 240v to the primary of the transformer from the main incoming 240v, and don't forget to earth things.