A single power line on USB 2.0 if I recall correctly can only carry 500mA at 5v, that's a whopping 2.5 watts.
That's not a lot of power.
You could easily tap the 5v line off a molex connector off the PC's CPU and get a lot more amps. The total amperage depending on PSU to PSU, however if you're powering LEDs it'd likely be more than enough.