I always preface everything with saying that I know only a fraction as some of these guys on here who've done a ton of cabinets... but t-molding is only a curvy as the wood it 'sticks' to. It comes down to really good cutting and sanding. You have to get the right jigsaw blade to cut those angles... obviously a wide blade can only really turn as wide as itself... there are blades that you can get anyway which are about 3/8 wide, specifically designed to cut curves. They are thin though, so they bend easy, especially when hot.
But you can cut a sharp corner then use a electric sander to round it off, it's all about patience. As a teenager, I used to sell a ton of skimboards to tourists (as my summer job, haha), ones that I handbuilt and I got pretty decent with a jigsaw, so cutting curves gets easier and easier with time. But don't try to mask things with your cab, take the time and do it right because you'll kick yourself down the line and want to go back and do it right but it'll be too late.
Also, when you sand your cabinet wall (as well as your 'width' supports, panels, etc.) stack them and sand them together, for instance, if one comes out 26" and the other is 25 5/8", and the other is 25 3/4", sand them ALL down to the shortest width (while stacked on top of each other). You can trace one on the other and it won't come out exactly as you planned it so sanding is where you make up the ground, make sure you were a mask though, you don't want to be breathing resin into your lungs.