Here is a better photo. It looks like it is a ground (an additional one?) like someone suggested.
It was me.... and yes, that's what it is.... It's not an additional one though. This is an electrical earth connection. It should be connected to the earth that comes in from your mains power lead. It's
not a low voltage ground (return) connection like the one that completes the circuit to your buttons.
This one is designed to conduct dangerous mains voltages away to earth in the event of a mains electrical fault. Rather than those voltages traveling through the pedals and you, in their attempt to get to earth.
However.... as you probably don't have anything that could cause the pedals to go live in the event of a mains fault, and they are probably only connected to the computer via the pots, (which is an LV low voltage conection) you actually should
leave that wire unconnected! In the actual event that there is a fault somewhere else in the cabinet, and mains voltage suddenly gets sent to earth via the mains earth tag... if that wire is connected your pedals would go mains live at the same time.
Best Regards,
Julian (Fozzy The Bear)