Zebidee, from what I understand of the PSON line, it is intended to bring a power supply out of a sleep state. Not bring the motherboard out of a sleep state.
When you send an ATX PC to sleep, it either puts a high impedence on PSON or lets PSON float. This forces the PSU into a sleep state, ie it should bring the power lines, except for Standby, down to 0v. The power button on your motherboard is really a soft switch. From almost any state, the motherboard will ground PSON thereby bringing the PSU up to a full power and allowing the entire PC operate.
When you operate the PSU without a MB, you
must ground PSON pin to get the PSU to operate properly. (On some, you even need to have a load on the power rail as well!). This is what you're describing.
Here's the rub, there is nothing that specifies that a MB MUST come out of a sleep state if something other than the MB grounds the PSON line. It's possible for some MB's to remain in a sleep state but the PSU will be powered.
There's also another problem. Some PC's (most notably those from Compaq) have all the appearances of an ATX standard PSU and Motherboard, however, the pinout and circuitry of said boards are
not ATX compliant nor compatible. On some models, swapping an ATX PSU into these crap boards will do nothing (at best) or pop a few components (at worst). As far as I know, there is no documentation readily available to determine the pinouts of these faux-ATX PSU's.
This will work like an on/off switch, not like a momentary on/off button that only SOME ATX MBs support.
No. not some, ALL. In my entire PC building career, I've yet to encounter an ATX complaint board lacking the the MOM power switch.
From reading your previous postings, it seems that there's some confusion on the different board standards there. In one of my posts, I specifically use AT boards as an example. That is
not a typo! I'm not writing AT* to include ATX, I'm specifically writing AT exclusive of ATX. There are many many motherboard standards out there. A small handful include XT, AT, Baby AT, ATX, BTX, and LPX. Wikipedia
compares some of the more well known form factors. It is a good launching point to learning the more common form factors you're likely to encounter.