Standard PC color coding is:
RED: 5V
YELLOW: 12V
ORANGE: 3.3V
BLACK: GROUND (power common tied to the earth line on the AC plug)
There's usually a sticker on the supply that details this, so verify if possible, but I've only once seen a PC supply that departed from this, and it was ancient.
Oh, a few more things: Note that this is not the same as what is fairly standard for arcade wiring, which uses orange for 12V. Also, if you have a multimeter, USE IT. Just check DC volts between the color of interest and black.