If you just want to use the lamps that are in the buttons to begin with, it would be best to know a little more about them, but they should work. I would pull out the lamp and see if I could find any information about the voltage and wattage. As long as the voltage is more than or equal to 12 volts you should use the 12 volts from your PC power supply, if it is between 5 and 12 volts use the 5. Running with less voltage than the lamp is rated for will make it a little dimmer, but actually make it last longer. As far as the wattage goes, as long as it is less than like 10 or so I wouldn't worry about it, especially if you are running a computer power supply of 300 watts or more.
Still the LEDs are a brighter, cooler, less power consuming option. With a little research you can find out which resisters to use to put the LEDs on the 5v from your PC. I think but am not sure and hopefully somebody will either confirm or deny this, that you can actually run two 3volt LEDs in series on the 5v line w/o any trouble.
Somebody please check that last statement, I am curious about it. Thanks.