I have seen MOST vectors in action (color and black&white), and it how correct, or good they look on a PC monitor really depends on the game.
Asteroids (and Deluxe, and most B&W vectors). Forget it, you THINK it looks good until you see a real one.
Tempest (most color vectors). PC can actually display this one fairly good. Not quite as bright though, and it is a bit TOO perfect, since every Tempest I have ever played has seemed to have had minor geometry issues.
Lunar Lander. I think this one looks better on PC. Played my first original one saturday, and I don't recall it pulling off any ultra-brightness tricks or anything, but it does flicker noticeably.
Also, one REAL issue for anyone wanting to do a vector Mame, is the fact that not all vector monitors are fast enough to display all games, and the fact that a B&W vector game will not look right on a color vector monitor (actually, B&W games NEVER look right on color monitors, raster or vector). Then there are also the overlays to think about, Lunar Lander, Battlezone, Asteroids Deluxe, Armor Attack, Star Castle, Warrior, and (I think) Demon all used overlays or backdrops that varied from simply decorative (Asteroids Deluxe, Star Castles), to being involved with game information (Battlezone, and the bezel on Lunar Lander), to being downright REQUIRED to properly play the game (Armor Attack, Warrior).