Why can I not use it the way I said, after the amp? And if I did, how could that hurt the amp considering it is after the amp and one way? If what you are saying is true, fine.. Just tell me why because I don't see how the setup I described effects the amp in any way. Also, I'm not going to be careless with the amp and blow it if I can help... It was around $25 so cheap but not something I want to just flush another $25 down the toilet. I saw this pot before I posted but it doesn't seem to match what I am looking for.. Doesn't have stereo input and output sides.
I actually did tell you why

. Amplifiers expect a certain load on the outputs, usually 4 or 8ohms. If you get too far away from this specification, components can overheat and die. There's a reason why you see speaker impedance switches on some amps, as well as switches to indicate how many speakers are connected. It's just like when using resistors (which are also loads). If you place two 8ohm resistors in series, it's a 16ohm load. If you place them in parallel, it's a 4ohm load. Depending on how speakers are connected to an amp, it does essentially the same thing. Running two 4ohm speakers in series on a single output channel of an amp designed for 8ohms is usually ok. Doing the same with 8ohm speakers usually isn't.
With a pot, you are adding additional load to the output, which, depending on the amp, you may (for a while) or may not get away with. But in any event, it's not the proper way to do what you want to do.
A simple DC power supply is a good example (although not exactly the same) of how a load affects things. It also has an "output". If the supply is designed to power a 2amp load, but you connect 5amps worth of stuff to it without a limiting fuse, it's going to first overheat, and then start killing off components.
If you note, the RCA connector device connects at the input side, as I suggested. One of the product questions (4th one down) is similar to what you want to do, and the answer indicates that the unit will not do it.