Both are putting out the same signal, so same quality.
Just make sure your video card is capable of putting out the correct signal and those adapters are wired correctly for it.
Really you should only use an adapter that the card came with originally.
It sounds like you understand how they work, but for those who might not:
Those things don't convert the signal, they just add a different connector type to your video card.
Just because the cable plugs in doesn't mean that the TV can make sense of the signal being sent to it.
Your video card will have to be set to output the correct type of signal for the TV.
This is done in the video card's software.
If the video card isn't sending the right type of output, it will be like trying to pick up an FM station with an AM radio.
Much better to do it this way than use a converter box that can add delay and other problems.
I run my old setup over S-video. It looks doesn't look nearly as good as when using component (using the s-vid connector pigtail),
but I have s-vid light guns, so have to stick to s-vid.