I tried putting mameui32 into a new directory, untouched, and dropped the "dkong" rom into the roms directory, ran an audit. Donkey Kong ran full screen, but I'm not sure if its using ArcadeVGA to its full ability because the default settings in mameui32 are "Direct3D" instead of "DirectDraw", and hardware stretching is on an switch res is off. I tried flipping those settings to the ones recommended by ArcadeVGA and it looked like hell, fuzzy and out of focus.