The 7-pin connector is probably not s-video. It is nVidia's solution to "HDTV" output and has composite, s-video, and component options on it. You will need a breakout cable to use it. Obtain the appropriate cable (should have come with the card), and set the TV out options to composite or s-video as you prefer. The breakout will have your standard yellow RCA composite jack and 4-pin mini-DIN s-video jack which you can then hook up to a modulator to feed a TV with only an RF tuner input.
If it is one of the (sadly rare) styles that will accept a 4-pin (not 5) s-video cables directly, you can use the appropriate adapter to get composite. Ideally, set your video card to output composite instead of s-video. This will usually turn on a filter that results in slightly higher quality video.