Well, I did some more testing with it (sending it off on Monday so thought I would have a go). After a bit of a warm up, the picture comes on but there's a definite issue with it. It looks almost like the picture is only being drawn at half the speed it should be, every other line being black instead of the correct colour, vertical frequency was also off. Still squealing like mad.
Oddly enough, I did a load more work on the 'sync' chassis and plugged that one in and that one is squealing too! Not as bad, and the picture looks fabulous (because all the components are near enough brand new now). I notice that the squealing gets much, MUCH worse whenever there the screen fades to black.
Very, very odd. o.o
Just to note, the 'sync' chassis still is out of sync. I've replaced just damn near about every component on it so I'm giving up hope for that =P It's odd, just this morning I found 2 dud resistors and replaced 3 new capacitors, including the mains smoothing cap which was the wrong value. And it still wont sync xD.