It will always overscan since that is how TVs operate, you dont have a black border when watching tv or a dvd.
Either get the service info for the tv (good luck on a house brand) to pull the image in, or make a lower res mode in powerstrip with the same clocks but less resolution so that you get a smaller image in the middle of the screen.
Otherwise if you can, try 576i, which is a pal mode and only 50 hz, this may let you see more of windows when you are in the UI, and the overscan will be correct(ish) once you launch a mame game at an arcade resolution