Here's how you'd write that script...
You could use something like PrintFolders to make a list of the contents of you 0.36 roms folder. Then edit the file in a text editor; do a find&replace to rename .zip to .png C:\036SNAPS\ , then add the word COPY to the start of each line (you could do this with a little macro in most text editors like Crimson Enditor or Ulta Edit). So now you've got a text file full of lines like COPY pacman.png C:\036SNAPS\ for each 0.36 rom. Save the file in your snaps folder, call it RUNME.BAT.
Make a folder on your C drive called 036SNAPS.
Run the RUNME.BAT that you created and it'll copy the png's for every 0.36 rom you've got into the C:\036SNAPS folder.