At work I mostly use Corel Draw 12, even though we have the full Adobe CS2 Suite. That said, I can't stand any of the other program in the Corel Suite- PhotoPaint is a poor PhotoShop wannabe- but if I have to do anything involving vectors, I'll stick with CorelDraw.
Nothing can touch PhotoShop for raster jobs, and the world knows it. But I've never seen a program that blends vector and raster components so easily as CorelDraw.