You could do it this way, if you have the drive space...
First off, unzip the new mame into it's directory (mame092_i686, or something like that).
Then use clrmamepro to create a dat file for that version of MAME and scan your OLD ROMS with the new DAT. You can then see what will be broken or what is missing and attempt to rebuild into the NEW ROM folder.
That's probably the best way to do it...because you keep your old ROMs intact while creating a new set.