I'm not sure if the voltages being sent to the neck are the same as the ones coming from your source signal, or if those 100 ohm resistors would be proper terminating loads depending on the impedance of the source signal. I believe most VGA termination requires 75 ohm. 100 is pretty close, but might cause some impedance mismatch and thus signal loss/reflection.
Ideally one would need an oscilloscope to compare a properly terminated input RGB signal going into a Jungle IC with the RGB signal coming out of the Jungle IC and going to the neckboard. This would show if there is any kind of signal processing, attenuation or amplification happening in the process. Meaning, if you are able to get this to work, more than likely you wont have any control over brightness, contrast, hue, color, tint, etc etc, as most of that is handled by the Jungle IC.
However, if you are intent on skipping the jungle IC anyways and injecting the signal after, then it seems there wouldn't be a need to disable the Jungle IC, which should allow you to insert the sync information into the composite signal and let the jungle IC operate per normal to do the sync. Of course, the caveat of this would be the need to disconnect the RGB output terminals from the jungle IC before injecting the signal into those traces. Perhaps terminate them into a 100ohm resistor sent to ground, then put a 75 or 100ohm resistor in series with the signal source before injecting them onto the traces.
If you decide to go that route, a triple pole double throw switch might let you switch between normal operation and the injected signal.