I took a bunch of picture and will update this post a little later after i get home for the day.
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EDIT: WARNING: imgur link (
http://imgur.com/a/F0Dh8)
links to an album of some photos that ark_ader is not allowed to click on because it contains unsafe practisces condoned by ark_ader such as: "Using utility knives" "Prying off the lids" and "Peering down the holes"i'm sitting on a butt load of old sealed lead acid batteries (SLAB's) from old uninterruptable power supplies etc. so ive been doing some experimenting with some actually pretty positive results.
so, we have a couple dozen batteries of various sizes from UPS's. we used to have UPS's in our jukeboxes, but the servicing of them was a nightmare. so, just for shits and giggles earlier this week (slow at work) I decided to peel apart one of these old SLAB's and see what the deal was. none of these batteries have been touched in probably 2 years at least. some have swelled cells in them (definitely toasted), others look fine.
I grabbed the biggest one we had (12 volt 20 amp hours) and threw the voltmeter on it.
1.34 volts...lovely. This has got some potential. the first thing i noticed was that there was a vent hole in the top and it looked like i could pry the whole cover off...which of course I did with the first tool I could find.
to my surprise i found a bunch of rubber vent caps under the lid. SWEET! i noticed they where all dimpled down. i peeled the first cap off and was greeted with a sucking WOOOSH as air entered the cell. i peered down to hole to see nothing. no water, no electrlyte. nothing. just the top of the cell.
i looked in all the cells and they all looked the same. i peeled open a swelled up battery and looked in the cells and noted they where VERY different looking. The good cells had a nice white appearance (the fiber mat) while the swelled up cells where all brown and burnt looking.
I decided I would try and see if I could get some of these batteries going again.
i immediately went to google to find out how these SLAB's are constructed. turns out they soak fiberglas pads in electrolyte and wrap/construct the cells with this mat or gel holding the electrolyte in place. The ‘valve’ is a is actually just a small loosely fit rubber cap, and because the plastic plate always being over it, can push upwards to release any gas due to overcharging, but will get sucked back down once pressure is reduced. Since sealed lead acid batteries recombine the oxygen and hydrogen produced at either plate, it typically never needs to vent, and when venting does occur, the recombining results in a negative pressure.
the water eventually evaporates away and the dry cells crap out.
so logic dictates i must resoak the mat with water. so i grab a jug of distilled water (we have lots of it for our forklift battery)hook up the meter and proceed to use a 10cc syringe to soak the pads in all the cells. after damn near 60 cc's in each cell i could see the water no longer absorbing into the mat. i chose to fill them a little more (just over the top of the cell.) just as a test.
i could visibly see the voltage of the battery change as i added water to the cells.
i waited about 15 or 20 minutes for the voltage to stabilize. after I had topped everything off my final voltage had dropped to about 1.09 volts. i drew off a small sample of liquid to see if there was any trace of acid left. I dropped a drop of liquid into some baking soada and observed no reaction. Water. alright. a trickle charger (15 volts output at 1500mA) was then applied to the battery. i measured about 15.5 volts @ 250mA being actually applied to the battery at first. (great internal resistance) i watched carefully for a few hours and monitored the temperature. I didn't feel like my piddly A/C adapter was going to cause the battery to blow up but i left all the caps off just to be sure.
I let the battery charge overnight. by the afternoon of the next day the voltage output by the charger had dropped to 13.8 volts and was pumping almost 600mA. ahhh progress. I drew off another sample and tested it again with the baking soda. a great fizzy reaction was observed. Sulphuric acid. AWESOME!
I disconnected the charger and let the battery stand for an hour or so. I tested the voltage and it settled in at 12.54 volts.
I'm going to leave this battery stand over the weekend and measure the voltage again and see where it sits. if it holds i'll do some stress tests with it and see if it has any amps left in it.
The problem with these batteries is the float charging that is applied to them in the UPS causes them to dry out. Acid remains, giving a full or near-full voltage reading with no load, however as soon as the battery has a real load (ie: the UPS switches over to battery power), little current can be provided by the small surface area of actual active plate area in contact with a dried out cell, and the voltage drops to near zero.
i'd like to mention also that if you do attempt to revive a SLAB, or any battery for that fact...
if you begin charging and encounter anything odd out of what i've described here...immediately STOP what you are doing.During this stage is when you should be monitoring for temperature increase, any hissing, or bubbling. a slightly increased temperature is to be expected...just slightly above cool metal, something like body temperature, anything warm or hot is not good, reduce charging current if you can or stop it completely.
If you do have a battery like this, it's best to to just toss it... You don't want one of these things blowing up on you.