Hi Muniosi,
You can't use GroovyArcade/GroovyMAME with a S-Video connection, it won't work. You need to use an RGB output (e.g. VGA to SCART).
The boot menu outputs at 31 kHz when using a proper RGB connection, so your picture showing it converted to 15 kHz was why VeS suggested me you were probably using a S-Video output.