PC power supplies always have their DC common (black wire) connected to earth ground (safety wire on the AC cord, usually green and sometimes with a yellow stripe).
If you wanted to float it, you could use a cheater plug, but be aware that this is a somewhat hazardous condition. At minimum, it will zap you if you complete the circuit to earth, but not badly if everything's operating correctly. The reason is that the EMI filter capacitors in the supply will leak about 60VAC to the DC common, but it's quite limited in current. Normally this just gets shunted away via the earth ground connection, but if you remove this connection by using a cheater plug or similar, it won't have that path.