Thanks for the advice information.
The Radeon 4870 is an excellent card but apparently not for the monitor I want to use.
I did get a DVI-I to BNC5 cable to try but I already took the 4870 out.
Will try the cable when I get the chance.
I decided to go with the PCIe ArcadeVGA 3000 instead.
I already had the ArcadeVGA2 and the ArcadeVGA 3000 adds some basic 3D capabilities.
What I am planning now is to add a second [smaller] 15 kHz monitor to my setup.
This would be for the usual suspects Nintendo Punch Outs and PlayChoice-10.
I am aware that PlayChoice-10 are basically just NES games but I remember playing them in the arcades so in they go.
The top screen will be a small CRT monitor probably a 13" as I don't want it to be to heavy or unstable as it sits on top of the 33".
I was inspired by the TopHead Dual-Screen MadEditor posted about in the Main forum section:

The size ratio of my CRT screens are similar.
I have some ideas that will hopefully allow the marquee to be displayed on the top screen when single screen games are played.
The trick will be getting the ArcadeVGA to operate two 15 kHz monitors. I have two PCIe ArcadeVGA cards but only one PCIe slot on my motherboards.
EDIT: The trick will be getting two ArcadeVGA cards in one system to operate the two 15 kHz monitors.