I have a question and don't get mad.....
why in the world are you using a scan converter to get composite out? If it's a geforce card then it should have composite out built in, and if it doesn't then a super crappy video card is the culprit.
Contrary to popular belief scan converters are extremely bad. Unless it's a broadcast quality converter, it's automatically 10 times worse than the tv out of any decent video card. Even with that aside though, they are generally used to convert the signal to go to an arcade monitor, not a tv. To run it through a converter is not only over complicating things but degrading the picture even more. Also many scan converters have to be re-centered when the screen resolution changes, so that is probably the reason you are having centering problems.
Also invidias utilities are crap, unfortunately. They usually cause more problems then they solve. Try disabling them all-together.