I found a program called Display Fusion and it works for some of the emulators but most launch into the 2nd monitor.
http://www.binaryfortress.com/displayfusion/I can get Mala over to my 2nd monitor no problem with a hotkey and manuever in it but most emulators when I launch them go back to the 1st monitor.
The only emulators that go to the 2nd monitor are: Mame, Mess, and Visualboyadvance although Mame and Mess are a little cut off which maybe I can tweak some more on that with resolutions.
The emulators that don't launch on the 2nd monitor are Atari800Win, Daphne, epsxe, fceultra, freedo, Fusion, handy, magic engine, project64, nebula, neo pop, nostalgia, stella, yabause, and zsnes.
Any ideas?

I see there is some kind of hotkey function in ATI control center so I'll check that out next.
Thanks,
Scott