At no point in the very loose specification do they define the gamut used for RGB over a scart because it was made to overlay captions rather then be the video signal when it was invented. Just like noone cares for accuracy of the colour red in their teletext pages, they would have seen no need for it when making the specification because there was no foreseeable reason that anyone would have anything better then a composite video signal coming in off air or cable back then.
If you take an old CRT tv with a scart, a sat reciever or dvd player with scart, plug them together with a fully wired cable, and use RGB chances are the colours will be wrong, and on a old CRT there is nothing you can do about it since the inputs go straight to the tube electronics. Later tvs seemed to see the problem and would drop it back to component internally and then process it as they do other stuff which would open up the warm, cool, etc whitepoints and in some cases tints and other rudimentary colour decoding controls to get things looking how you like.
If there was a need for adiquite cable that should have being part of the specification that a cable would have less then x dB crosstalk between the signals. The spec didnt cover something that IMO is a fundimental part of an interconnection between 2 devices. Imagine if ethernet had never specified cat-5 or whatever so people would sell ethernet cables which would never work? Seems unthinkable but yet they did it with scart.
Scart made it really hard in the early days of home theatre when you had a mono TV, a stereo VCR and wanted audio to go to a separate system, you had to dick around with scart splitters, and more cables, or else adapt to the RCA plugs that they were intent on replacing, and then run cables to where you wanted them to go - in a way thats no better then HDMI is now, but it was a massive problem before they seemed to wise up and put RCA outs on VCR's as well.
A source has no idea what phosphers are in use on the tube, its up to the colour decoder to dematrix a signal and put the right amounts to each gun or whatever - trivial to do on a PC in software now, but was a total ---smurfette--- to do in the analog domain so generally people just put up with bad colours - look at the old conversions of NTSC stuff for an example of uncorrected colourspace translations, and someone on here was recently posting about obama being green which would have being from something similar.