I'm not sure I understand what you're trying to do. If you're simply trying to center multiple objects, all you need to do is select them all and then use the horizontal and/or vertical centering commands in the "Align" pallette. It's also much more acurate than trying to do it manually.
This can be combined with grouping if, for example, you have two items that need to stay together or a distance apart. In the first example I grouped the two eye shapes. When center aligned, they are centered as a grouped object and therefore keep their spacing.
Maybe if you could give a more detailed description of what you're trying to do we might be able to give you more specific tips.