I have been thinking the same thing... The order of things.
It has been since Win95 that I have even dabbled in writing a batch file.

So I may need some folks to hold my hand! I presume I could delete my current HS and MH shortcuts from the Startup folder and then add the created Batch file to the startup folder?
Do I need any kind of pause between them?
Does something like this look closse to correct?
@echo off
start "mamehooker" "c:\mamehooker\mamehooker.exe"
start "hyperspin" "c:\hyperspin\hyperspin.exe"
Again...years since I did this...mainly just checking on the commands...
Thanks again!