I used an old CD audio cable I had laying around. I cut down the one molex to 2 connectors with a razor knife. I cut off the other molex and crimped those wires to quick disconnects.
That's what I did as well... just to clarify it's the "audio" cable that would run from old CD rom drives to your soundcard.
I'm sure rat shack has 'em you just need to be able to find a reasonably competant employee (good luck) and be able to show picture or explain it properly --- Oscar knows the technical name for the type of plug we're talking about.
Regardless, this shouldn't be this hard. If you are using an existing PC in a case there's already a run of wire from the momentary switch on the front of your PC case to your motherboards power switch. If you are so inclined... cut it in the middle and extend the wires to a different momentary pushbutton or to an arcade button.
I mean, you are turning on your PC somehow now... just make the wire longer to a "new" switch... *shrug*
Rampy
If you're really squeemish you could just set your bios to startup by key stroke so say... hitting a pushbutton wired through a keyboard enocder will turn on your system... or set in your bios power up after power failure/etc...