1) The same button thats used for start up, go into your pc settings and set up and set it so that when you press the pc front button, it shuts down.
In xp, its Start
-control panel
-power options
-advanced
then select shutdown in the drop down box
or
You can set up your frontend (depending on which one, but both Mala and Hyperspin will do it) to shutdown the pc upon exiting.
2) I'm not sure what you're asking here. I understand voltage drops across leds and all that but what is asking for your voltage drop. are you trying to determine what resistor to use in series? if you are using rgb leds from groovy game gear, the resistors are already a part of the unit and they are ready for 5 volts.