AT power supplies use ON/OFF, ATX uses momentary ON.
The advantage of ATX is that under modern OSes like WinXP, the ATX power ON switch will also initiate the soft shutdown command for the system. Very handy.
For ATX folks, just wire up a standard microswitch (a typical arcade fire button and microswitch works fine) to the ATX-power-ON header on your motherboard. It's as simple as that. One click for startup, and one click for clean shutdown.
Just remember to disconnect it when removing the PC from your cab!