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Spacedueler:

Yes  - sounds like a cure issue. Some of the Rustoleum sprays say "recoat within 2 hours or AFTER 40." After 2 hours the paint is only partially cured. The solvent in the fresh paint will cause the prior coat to wrinkle if it is partially cured (basically the first coat isn't tough enough, and the second coat is acting like a paint stripper). I found out the hard way myself thinking 24 hours was enough - I won't make that mistake again.

apfelanni:

some spraycanpaints have very aggressive solvents , especially car paintings / fillers / primers. some resin paintings take weeks or even months to harden , depending on the weather conditions and the thickness . rule number one is to make sure all paint and varnish is compatible , best from one producer. rule number two is be patient and dont rush anything when it comes to painting . if the temps or humidity doesnt match ,  u better dont even try the paintjob. 

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